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Hydrido(carbene), Hydrido(diazoalkane), Aqua(carbene), and Vinyl(carbene) Complexes of Osmium(II)

✍ Scribed by Helmut Werner; Wolfram Stüer; Justin Wolf; Matthias Laubender; Birgit Weberndörfer; Regine Herbst-Irmer; Christopher Lehmann

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
423 KB
Volume
1999
Category
Article
ISSN
1434-1948

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✍ Helmut Werner; Wolfram Stüer; Birgit Weberndörfer; Justin Wolf 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 353 KB 👁 2 views

The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 • 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit