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Hydrido-silyl complexes, Part VIII. Photochemical reaction of [Fe(CO)3H(PR′3)SiR3] with silanes, HSiR3: Influence of PR′3and SiR3on formation and structures of bis-silyl complexes [Fe(CO)3(PR′3)(SiR3)2]

✍ Scribed by Michael Knorr; Ulrich Schubert

Publisher: Springer
Year: 1986
Tongue: English
Weight: 486 KB
Volume: 11
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00959930

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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo