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Hydride transfer versus electron transfer in the reduction of 4-phenyl-3-halo-3-buten-2-ones mediated by Pichia stipitis

✍ Scribed by Dávila S. Zampieri; Luiz A. Zampieri; J. Augusto R. Rodrigues; Bruno R.S. de Paula; Paulo J.S. Moran


Book ID
113804889
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
294 KB
Volume
72
Category
Article
ISSN
1381-1177

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Concerning the reduction of alkyl halide
✍ E.C. Ashby; R.N. DePriest; T.N. Pham 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The reduction of lo and 2' alkyl iodides by LiA1H4.has been shown to involve a radical intermediate formed by the reaction of the alkyl iodide with the AlH3 and LiI produced in situ in conjunction with LiAlH4 rather than by LiAlH4 alone, as evidenced by cyclized products in the reduction of 6-iodo-1