Hydration of Lanthanoid(III) Ions in Aqueous Solution and Crystalline Hydrates Studied by EXAFS Spectroscopy and Crystallography: The Myth of the “Gadolinium Break”
✍ Scribed by Ingmar Persson; Paola D'Angelo; Simone De Panfilis; Magnus Sandström; Lars Eriksson
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 516 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
Mid infrared, far-infrared and Raman spectroscopic studies, combined with force field analyses, were performed for the hydrated platinum(II) and palladium(II) ions and cis-diammineplatinum(II) complex in acidic aqueous solutions. Simplified Density Functional Theory (DFT) calculations were made for
ionic coordiirion \vns investi@ed in Pe(NOa)s aqueous soiutions by X-ray diffraction\_ The eaperimental correlatton Function appears to be mainly characterized by the hydration of the cation. Satisfactory agreement with experimental datd is achieved through a mode! in nhich the nitrate ions arc cons