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An X-ray diffraction study on the first and the second hydration shell of the Fe(III) ion in nitrate solutions

✍ Scribed by R. Caminiti; M. Magini

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 385 KB
Volume: 61
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)85080-0

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✦ Synopsis

ionic coordiirion \vns investi@ed in Pe(NOa)s aqueous soiutions by X-ray diffraction_ The eaperimental correlatton Function appears to be mainly characterized by the hydration of the cation. Satisfactory agreement with experimental datd is achieved through a mode! in nhich the nitrate ions arc considered devoid of any discrete interaction with the surrounding moIecuIes. and the PC 3t ions have an inner hydration shell of six water molecules octnhedrnlly m-mn~ed, nnd n second shell of twelve water molecules.

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