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Hydration effects on SN2 reactions: an integral equation study of free energy surfaces and corrections to transition-state theory

✍ Scribed by Huston, Shawn E.; Rossky, Peter J.; Zichi, Dominic A.

Book ID: 126159286
Publisher: American Chemical Society
Year: 1989
Tongue: English
Weight: 997 KB
Volume: 111
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00197a027

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📜 SIMILAR VOLUMES

Solvent effects on the free energies of

Solvent effects on the free energies of ion-pairs, and of transition states in an SN1 and an SN2 reaction

✍ M.H. Abraham 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 181 KB

The influence of solvents on the free energy of activation in the ionisation of t-butyl chloride may be dissected into initial-state and transition-state contributions through equation (I), where AGz(T) AG;([B.&l]\*) = AG;(Bu%l)