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Solvent effects on the free energies of ion-pairs, and of transition states in an SN1 and an SN2 reaction

✍ Scribed by M.H. Abraham

Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 181 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99982-9

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✦ Synopsis

The influence of solvents on the free energy of activation in the ionisation of t-butyl chloride may be dissected into initial-state and transition-state contributions through equation (I), where AGz(T) AG;([B.&l]*) = AG;(Bu%l)

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