Hybrid materials composed of tetravanadate motifs: Synthesis, structure and magnetic properties of the open framework structure solids [{M(C5H5N)4}2]V4O12 (M = Cu, Co)
β Scribed by M. Ishaque Khan; Renata C. Nome; Naga Ravikanth Putrevu; James H. McNeely; Brant Cage; Robert J. Doedens
- Book ID
- 108138361
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 680 KB
- Volume
- 363
- Category
- Article
- ISSN
- 0020-1693
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A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU