Hybrid Copolymerization of ε-Caprolactone and Methyl Methacrylate
✍ Scribed by Yang, Hongjun; Xu, Jinbao; Pispas, Stergios; Zhang, Guangzhao
- Book ID
- 120493537
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 686 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0024-9297
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Macromonomeric azo initiator containing biodegradable poly( 1-caprolactone, (PCL) was synthesized by the condensation reaction of PCL with 4,4 -azobis(4cyanopentanoyl chloride) and methacryloyl chloride. This macromonomeric azo initiator (MIM-PCL) was further used in the polymerization of styrene (S
The cloud points for the co-nonsolvent systems (it pyridine (PY) + formic acid (FA) towards poly(e-caprolactone) (PCL) or poly(methyl methacrylate) (PMMA) and (ii) pyridine + acetic acid (AA) towards PCL have been experimentally determined as a function of solvent composition at fixed polymer concen
## Abstract Poly(methyl methacrylate)‐poly(__ε__‐caprolactone) (PMMA/PCL) microparticles were synthesized by suspension polymerization of methyl methacrylate in the presence of PCL. The incorporation of a small amount of a macromonomer, methacryloyl‐terminated PCL (M‐PCL), into the reaction mixture
a-Chloromethyl-a-methyl-b-propionolactone (CMMPL) has been copolymerized with e-caprolactone (CL) using a wide range of feed compositions and aluminium triisopropoxide [Al(O i Pr) 3 ] as an initiator. Random copolymers of CMMPL with CL were obtained. The pendant chloromethyl groups of the copolymer