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Homopolymerizations of Methyl Methacrylate and Styrene: Chain Transfer Constants from the Mayo Equation and Number Distributions for Catalytic Chain Transfer, and the Chain Length Dependence of the Average Termination Rate Coefficient

โœ Scribed by Suddaby, K. G.; Maloney, D. R.; Haddleton, D. M.

Book ID
118177111
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
327 KB
Volume
30
Category
Article
ISSN
0024-9297

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## Abstract **Summary:** The RAFTโ€CLDโ€T methodology is demonstrated to be not only applicable to 1โ€substituted monomers such as styrene and acrylates, but also to 1,1โ€disubstituted monomers such as MMA. The chain length of the terminating macromolecules is controlled by CPDB in MMA bulk free radica