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Homolytic rearrangement with the migration of an alkylthio or arylthio group

✍ Scribed by A. B. Terent'ev; R. G. Petrova


Book ID
112419228
Publisher
Springer
Year
1963
Tongue
English
Weight
241 KB
Volume
12
Category
Article
ISSN
1573-9171

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Ketene Formation or Phenyl-Group Migrati
✍ Evangelos G. Bakalbassis; Spyros Spyroudis; Constantinos A. Tsipis πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 439 KB

## Abstract Phenyliodonium ylides of hydroxyquinones easily undergo intramolecular rearrangements associated with phenyl‐group migration or ketene formation under ambient conditions. The mechanism of the two rival potential reaction paths was explored by electronic structure calculation techniques