Homogeneous Pd-Catalyzed Transformation of Terminal Alkenes into Primary Allylic Alcohols and Derivatives
β Scribed by Tomita, Ren; Mantani, Kohei; Hamasaki, Akiyuki; Ishida, Tamao; Tokunaga, Makoto
- Book ID
- 125416587
- Publisher
- John Wiley and Sons
- Year
- 2014
- Tongue
- English
- Weight
- 315 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0947-6539
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## Abstract This review describes the different Pdβcatalyzed methods that afford allylic amines from intermolecular reactions between allylic alcohols and amines and, with personal comments, the mechanisms that have been proposed. Allylic amines are an important class of compounds, while a wide str
Triethylborane promotes the Pd-catalyzed selective C-diallylation of o-hydroxyacetophenone and C-monoallylation of o-hydroxypropiophenone with a variety of ally alcohols. The reaction proceeds smoothly at 25-50Β°C and provides the allylation products in excellent yields.