Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes
β Scribed by Lim, Hwan Jung; Smith, Craig R.; RajanBabu, T. V.
- Book ID
- 120364321
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 270 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract Ruβcatalyzed [2+2] cycloadditions between bicyclic alkenes and alkynyl halides were found to occur in moderate to good yields. The presence of the halide moiety greatly enhances the reactivity of the alkyne component in the cycloaddition and can be transformed into a variety of products
Selective Wacker-type oxidation of long-chain terminal alkenes to methylketones was successfully achieved by using Pd(OAc) 2 /molybdovanadophosphate (NPMoV)/O 2 system. The selectivity of the reaction increased by slow addition of the alkenes to the catalytic solution. The oxidation of a,v-dienes wa