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Homogeneous catalytic transformation of aryl-substituted epoxides by some complexes of the platinum metals

✍ Scribed by David Milstein; Ouri Buchman; Jochanan Blum


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
196 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis


Numerous examples have been reported1

wherein acids, bases or salts catalyzed the rearrangement of substituted ethylene oxides. However, only a few cases are known in which transition metal complexes promote the homogeneous transformation of internal epoxides to ketones.

Cobalt and iron


πŸ“œ SIMILAR VOLUMES


Catalytic polarographic reduction of hyd
✍ M. Ostern; J. Biernat; B. JeΕΌowska-Trzebiatowska πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 English βš– 589 KB

The catalytic polarographic reduction of hydrogen ions in the presence of thiocyanatoplatinum(II) and (IV) complexes has been studied. The catalytic inactivity of the Pt(SCN),8-ions shows that the evolution of hydrogen can be only catalysed by the planar thiocanato complex of platinum(H). A specific