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Homogeneous catalytic carbonylation of nitroaromatics. 2. Characterization of two intermediates, Ru[C(O)N(Ar)O][Ph2P(CH2)2PPh2](CO)2 and Ru[C(O)OCH3]2[Ph2P(CH2)2PPh2](CO)2, and evidence for the carbamate-forming step

✍ Scribed by Gladfelter, Wayne L.; Gargulak, Jerry D.; Noirot, Mark D.


Book ID
111913569
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
272 KB
Volume
113
Category
Article
ISSN
0002-7863

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Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac