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Homogeneous catalysis. Metal catalyzed Claisen rearrangements of allylic thionobenzoates

✍ Scribed by Auburn, Pamela R.; Whelan, John.; Bosnich, B.


Book ID
126176641
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
629 KB
Volume
5
Category
Article
ISSN
0276-7333

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Palladium(II)-catalyzed claisen rearrang
✍ J.L van der Baan; F Bickelhaupt πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 258 KB

The Claisen rearrangement of ally1 vinyl ethers is catalyzed by PdCQ(CH3CN)Z. provided that alkyl substituents protect the vinyl ether double bond from coordination by the metal catalyst. [3,3]Sigmatropic rearrangements are very useful for the formation of C-C, C-O, C-N and C-S bonds. Besides the cl