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Catalyzed Claisen rearrangements of O-allyl kojates

✍ Scribed by Pirrung, Michael C.; Nalbandian, Jenifer N.


Book ID
120422695
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
422 KB
Volume
54
Category
Article
ISSN
0040-4039

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Palladium(II)-catalyzed claisen rearrang
✍ J.L van der Baan; F Bickelhaupt πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 258 KB

The Claisen rearrangement of ally1 vinyl ethers is catalyzed by PdCQ(CH3CN)Z. provided that alkyl substituents protect the vinyl ether double bond from coordination by the metal catalyst. [3,3]Sigmatropic rearrangements are very useful for the formation of C-C, C-O, C-N and C-S bonds. Besides the cl