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Homogeneous and heterogeneous olefin epoxidation catalyzed by a binuclear Mn(II)Mn(III) complex

✍ Scribed by Silvana T. Castaman; Shirley Nakagaki; Ronny R. Ribeiro; Kátia J. Ciuffi; Sueli M. Drechsel

Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
770 KB
Volume
300
Category
Article
ISSN
1381-1169

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The polymer supported Mn(II) Schiff base complexes were prepared from crosslinked chloromethylated poly(styrene-divinyl benzene) copolymer beads by sequential modification into a Schiff base bearing ligand. These Schiff base bearing polymer on treatment with a solution of MnCl 2 •2H 2 O gave the cor