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Selective epoxidation of unfunctionalized olefins catalyzed by unsymmetric Mn(III)-Schiff base complexes

✍ Scribed by Xiang-Dong Du; Xian-Da Yu

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
445 KB
Volume
126
Category
Article
ISSN
1381-1169

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Synthesis of catalytically active polymer-bound Schiff base manganese complexes for selective epoxidation of unfunctionalized olefins
✍ Xiang-Dong Du; Xian-Da Yu πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 124 KB πŸ‘ 2 views

A polymerizable unsymmetric tetradentate Schiff base with one vinyl group 3 was synthesized and copolymerized with styrene in toluene. Mn(III) ion was quantitatively incorporated into the copolymers by the functional moieties. The resulting linear polymer-bound manganese complexes ( 4a and 4b) were