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Homogeneous and heterogeneous alkyl-alkoxo-lanthanide type catalysts for polymerization and block-copolymerization of ethylene and methyl methacrylate

✍ Scribed by Jérôme Gromada; Thomas Chenal; André Mortreux; Frédéric Leising; Jean-François Carpentier

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
106 KB
Volume
182-183
Category
Article
ISSN
1381-1169

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Synthesis and application of pendant phenyl cyclopentadienyl lanthanide chlorides as catalyst precursors for methyl methacrylate polymerization
✍ Xiaomin Xie; Jiling Huang 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 1 views

The synthesis and characterization of a series of new pendant phenyl substituted cyclopentadienyl lanthanide chlorides are reported. The analytical data of 3a-3e point to the formation of monomeric and unsolvated complexes, (PhCMe 2 C 5 H 4 ) 2 LnCl (Ln = Er (3a), Sm (3b), Gd (3c), Y (3d), Nd (3e));