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Homo-dinuclear hexadentate copper(II) and nickel(II) cryptates: Synthesis, spectroscopic and electrochemical characterization of the perchlorate salts

✍ Scribed by K. Ragunathan; Parimal K. Bharadwaj


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
430 KB
Volume
14
Category
Article
ISSN
0277-5387

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Template Synthesis, Crystal Structure, a
✍ Peter Comba; Trevor W. Hambley; Geoffrey A. Lawrance πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 German βš– 606 KB

In a facile carbon-acid condensation reaction of bis(2-aminomethylpyridine)copper(II) with nitroethane and formaldehyde in basic MeOH the N,N' -bis(2-pyridylmethylene)-l,3-diamino-2-methyl-2-nitropropane)copper~I~) cation is produced in essentially quantitative yield. The perchlorate salt crystalliz