The first dinuclear orotate complex: Syntheses, spectral, thermal and structural characterization of supramolecular orotate complexes of nickel(II) and copper(II) with 2-hydroxyethylpyridine
✍ Scribed by Okan Zafer Yeşilel; Aylin Mutlu; Cemil Öğretir; Orhan Büyükgüngör
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 901 KB
- Volume
- 889
- Category
- Article
- ISSN
- 0022-2860
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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~
New lead(II)-saccharin complexes, [Pb(sac) 2 (pym)] (1) and [Pb(sac) 2 (pydm)] (2) (sac ϭ saccharinate anion; pym ϭ 2-pyridylmethanol; pydm ϭ pyridine-2,6-dimethanol) were synthesized and characterized by IR spectroscopy and single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclin