Homo- and hetero-bridged mixed-valence dinuclear complexes which contain the fragment ‘Rh(C6F5)3’

Synthesis of Homo- and Hetero-Bimetallic

Synthesis of Homo- and Hetero-Bimetallic Complexes Containing the Ni(C6F5)2 Moiety – Crystal Structure of [(C6F5)2Ni(μ-SPh)2Pd(dppe)]

✍ Gregorio Sánchez; Francisca Momblona; Mateo Sánchez; José Pérez; Gregorio López; 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 333 KB 👁 1 views

The compound cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] has been used as the between [(C 6 F 5 ) 2 Ni(&µ-X) 2 Ni-(C 6 F 5 ) 2 ] 2-and L. The treatment of cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] with [M(SAr) 2 (dppe)] leads to the starting material for the preparation of the bimetallic complexes ethane], and the Pt). Th