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Homo- and copolymerizations of butadiene and styrene with Ln(OCOCOl3)3-based catalyst

✍ Scribed by Shojiro Kaita; Eiichi Kobayashi; Sayuri Sakakibara; Sadahito Aoshima; Junji Furukawa


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
306 KB
Volume
34
Category
Article
ISSN
0887-624X

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Homo-and copolymerizations of butadiene (BD) and styrene (St) with rareearth metal catalysts, including the most active neodymium (Nd)-based catalysts, have been examined, and the cis-1,4 polymerization mechanism was investigated by the diad analysis of copolymers. Polymerization activity of BD was

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Copolymerization of styrene (St) and butadiene (Bd) with nickel(II) acetylacetonate [Ni(acac) 2 ]-methylaluminoxane (MAO) catalyst was investigated. Among the metal acetylacetonates [Mt(acac) x ] examined, Ni(acac) 2 showed a high activity for the copolymerization of St and Bd giving copolymers havi