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Copolymerization of styrene and butadiene with Co(acac)3-methylaluminoxane catalyst

✍ Scribed by Kiyoshi Endo; Yuichi Matsuda


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
82 KB
Volume
201
Category
Article
ISSN
1022-1352

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Copolymerization of styrene and butadien
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Copolymerization of styrene (St) and butadiene (Bd) with nickel(II) acetylacetonate [Ni(acac) 2 ]-methylaluminoxane (MAO) catalyst was investigated. Among the metal acetylacetonates [Mt(acac) x ] examined, Ni(acac) 2 showed a high activity for the copolymerization of St and Bd giving copolymers havi

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Homo-and copolymerizations of butadiene (BD) and styrene (St) with rareearth metal catalysts, including the most active neodymium (Nd)-based catalysts, have been examined, and the cis-1,4 polymerization mechanism was investigated by the diad analysis of copolymers. Polymerization activity of BD was