Histidine-functionalized silica and its copper complex as stationary phases for capillary electrochromatography
β Scribed by Tse-Shien Chen; Chuen-Ying Liu
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 125 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0173-0835
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The feasibility of enantiomer separation by capillary electrochromatog-Ε½ . Ε½ . raphy CEC was shown on 75-m i.d. capillary columns packed with 3-m bare w Ε½ . silica packings. Racemic phenylephrine 3-hydroxy-β£methylaminomethyl benzyl x w Ε½ . x alconhol and synephrine 4-hydroxy-β£-methylaminomethyl ben
Chromatographic silica (10 lm) was chemically modified with the silylating agent: [3-(2-aminoethyl)aminopropyl]trimethoxysilane (AEAPTS). The reaction product was characterized by elemental analysis and infrared and 13 C and 29 Si NMR spectra. The chemically modified silica was treated with Cu(II) i
A silica-based stationary phase with surface bound silylpropyl trialkylammonium functions was introduced and evaluated in the capillary electrochromatography of alkylbenzenes and pesticides. This stationary phase is referred to as octadecyldimethyl(3-trimethoxysilylpropyl) ammonium-silica (ODAS) and