The inductive properties of a non-polar diatomic molecule in a static non-uniform electric field are best described in terms of its dipole polarizability (a), second hyperpolarizability (y), quadrupole-quadrupole polarizability (C) and dipole-dipole-quadrupole polarizability (B). We present formulae
Hindered rotation and external electric field effect of adsorbed diatomic molecules
โ Scribed by Y.T. Shih; D.S. Chunu; W.N. Mei
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 657 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0038-1098
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๐ SIMILAR VOLUMES
For the vibration-rotational motion of a diatomic molecule, various forms of an effective Hamiltonian which includes the corrections of the Born-Oppenheimer approximation in the form of radial functions are reviewed. A procedure to fit vibration-rotational and pure rotational transitions is proposed
The effect of possible large electric field gradients near metal surfaas on the Raman optical activity (ROA) of adsorbed molecules is discussed. It is shown that large gradients would cause unusually high values of the measured circular intensity differences, orders of mapitude higher than those mea
Fluorescence quenching by an external electric field (E) is observed in pyrimidine vapor on excitation into S, under the collision-free conditions. Fluorescence decay is also found to be affected by E. The electric field effects both on intensity and decay are interpreted in terms of a field-induced