The voltage dependence of the SER spectra of adsorbed ATP molecules has been found to vary with the pH values of the solutions. The differences in the spectra are explained by the protonation of the adsorbed ATP molecules.
β¦ LIBER β¦
The effect of large electric field gradients on the Raman optical activity of molecules adsorbed on metal surfaces
β Scribed by S. Efrima
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 347 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The effect of possible large electric field gradients near metal surfaas on the Raman optical activity (ROA) of adsorbed molecules is discussed. It is shown that large gradients would cause unusually high values of the measured circular intensity differences, orders of mapitude higher than those measured in solution_ ROA may be used to investigate the csistence of
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