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Highly Versatile Enantioselective Conjugate Addition of Grignard Reagents to α,β-Unsaturated Thioesters

✍ Scribed by Maciá Ruiz, Beatriz; Geurts, Koen; Fernández-Ibáñez, M. Ángeles; ter Horst, Bjorn; Minnaard, Adriaan J.; Feringa, Ben L.


Book ID
126171677
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
57 KB
Volume
9
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES


Catalytic enantioselective conjugate add
✍ Motomu Kanai; Yuichi Nakagawa; Kiyoshi Tomioka 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 781 KB

A catalytic asymmetric conjugate addition reaction of organocopper reagents, generated from copper salt, a chiral phosphine, and Grignard reagent, with cyclohexenone is highly dependent on the counter anion of copper species, solvents, Grignard reagents, and the structure of the chiral phosphine. Th