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Highly Unsaturated Phosphorus Compounds: Generation and Reactions on Both Multiple Bonds of Vinyl Phosphaalkyne†

✍ Scribed by Ionkin, Alex S.; Marshall, William J.; Fish, Brian M.; Schiffhauer, Matthew F.; Davidson, Fredric; McEwen, Charles N.

Book ID: 111644053
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 211 KB
Volume: 28
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om801224d

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Highly unsaturated phosphorus compounds:

Highly unsaturated phosphorus compounds: Trimeric and dimeric sulfides of a α,β-di-tert-butyl vinyl phosphaalkyne

✍ Alex S. Ionkin; William J. Marshall; Brian M. Fish 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB 👁 1 views

## Abstract The first examples of sulfides of a 1,3,5‐triphosphabenzene were synthesized by the sulfurization of parent 1,3,5‐triphosphabenzene **2**. Disulfide **7** was found to be remarkably thermally stable, the stability likely coming from the contribution of resonance forms **7A** and **7B**.

ChemInform Abstract: Highly Unsaturated

ChemInform Abstract: Highly Unsaturated Phosphorus Compounds: Trimeric and Dimeric Sulfides of a α,β-Di-tert-butyl Vinyl Phosphaalkyne.

✍ Alex S. Ionkin; William J. Marshall; Brian M. Fish 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views