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ChemInform Abstract: Highly Unsaturated Phosphorus Compounds: Trimeric and Dimeric Sulfides of a α,β-Di-tert-butyl Vinyl Phosphaalkyne.

✍ Scribed by Alex S. Ionkin; William J. Marshall; Brian M. Fish


Publisher
John Wiley and Sons
Year
2011
Weight
28 KB
Volume
42
Category
Article
ISSN
0931-7597

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Highly unsaturated phosphorus compounds:
✍ Alex S. Ionkin; William J. Marshall; Brian M. Fish 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB

## Abstract The first examples of sulfides of a 1,3,5‐triphosphabenzene were synthesized by the sulfurization of parent 1,3,5‐triphosphabenzene **2**. Disulfide **7** was found to be remarkably thermally stable, the stability likely coming from the contribution of resonance forms **7A** and **7B**.