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Highly stereoselectively cope rearrangements of enantiomerically pure, silylated syn-aldols

✍ Scribed by Christoph Schneider; Markus Rehfeuter

Book ID: 104207357
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 983 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(96)00958-1

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✦ Synopsis

Enantiomerically pure, 1,6_disubstituted l&dienes 3a-k with an aldol subtitution pattern undergo rapid thermal Cope rearrangements with very high diastereoselection (up to >97:3) and in very good yield.

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