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ChemInform Abstract: Stereoselective Cope Rearrangements of syn- and anti-Aldol Products.

✍ Scribed by C. SCHNEIDER; M. REHFEUTER


Book ID
112034258
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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Highly stereoselectively cope rearrangem
✍ Christoph Schneider; Markus Rehfeuter πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 983 KB

Enantiomerically pure, 1,6\_disubstituted l&dienes 3a-k with an aldol subtitution pattern undergo rapid thermal Cope rearrangements with very high diastereoselection (up to >97:3) and in very good yield.