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Highly stereoselective synthesis of cyclic primary amines via hydride reductions.

✍ Scribed by Robert O. Hutchins; Wei-Yang Su

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 218 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80002-2

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## Abstract A practical and selective method for the synthesis of the β‐arylamines 5 and the __cis__‐ or __trans__‐amino alcohols 8 or 11 is reported. The reaction sequence starts from α‐tetralones 1 which readily react with dibenzyl azodicarboxylate to afford the protected α‐hydrazino ketones 2. T