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Highly Enantioselective Hydrogen-Transfer Reductive Amination: Catalytic Asymmetric Synthesis of Primary Amines.

✍ Scribed by Renat Kadyrov; Thomas H. Riermeier

Publisher: John Wiley and Sons
Year: 2004
Weight: 123 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200411032

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## Abstract A variety of aromatic and aliphatic imines is smoothly hydrogenated in the presence of an iron—diphosphine catalyst to give the corresponding amines (II), (IV) or (VI) in good yields and high enantioselectivities (up to 98% e.e.).