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ChemInform Abstract: Enantioselective Synthesis of Amines: General, Efficient Iron-Catalyzed Asymmetric Transfer Hydrogenation of Imines.

✍ Scribed by Shaolin Zhou; Steffen Fleischer; Kathrin Junge; Shoubhik Das; Daniele Addis; Matthias Beller

Publisher
John Wiley and Sons
Year
2011
Weight
52 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A variety of aromatic and aliphatic imines is smoothly hydrogenated in the presence of an ironβ€”diphosphine catalyst to give the corresponding amines (II), (IV) or (VI) in good yields and high enantioselectivities (up to 98% e.e.).

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