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Highly Stereoselective Synthesis of Arylene-Silylene-Vinylene Polymers

✍ Scribed by Mariusz Majchrzak; Bogdan Marciniec; Yujiro Itami


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
259 KB
Volume
347
Category
Article
ISSN
1615-4150

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✦ Synopsis


Dedicated to Professor Julian Chojnowski on the occasion of his 70 th birthday in recognition of his significant contribution to organosilicon polymer chemistry.


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Synthesis of silylene-vinylene oligomers
✍ Bogdan Marciniec; Mariusz Lewandowski πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 217 KB πŸ‘ 1 views

Acyclic diene polymerization (ADP) of divinyldimethylsilane in the presence of ruthenium RuCl,(PPh,), and rhodium [RhCl(cod)I2 catalysts led predominantly to linear silylenevinylene oligomers ( M , = 1510 and M J M , = 1.19) if the ruthenium catalyst was used or to mixture of cyclic and linear oligo