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Synthesis of silylene-vinylene oligomers via catalytic polycondensation of divinyldimethylsilane

✍ Scribed by Bogdan Marciniec; Mariusz Lewandowski

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 217 KB
Volume: 34
Category: Article
ISSN: 0887-624X
DOI: 10.1002/(sici)1099-0518(199606)34:8<1443::aid-pola7>3.0.co;2-0

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✦ Synopsis

Acyclic diene polymerization (ADP) of divinyldimethylsilane in the presence of ruthenium RuCl,(PPh,), and rhodium [RhCl(cod)I2 catalysts led predominantly to linear silylenevinylene oligomers ( M , = 1510 and M J M , = 1.19) if the ruthenium catalyst was used or to mixture of cyclic and linear oligomers if rhodium complex was catalyst. 0

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