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Highly Stereoselective Synthesis of 1,2-Diorganothio-1-alkenes via Hydrothiolation of Alkynyl Sulfides Catalyzed by Cesium Hydroxide

✍ Scribed by Ping Tan; Xianhong Yin; Aihe Yu; Renhua Qiu; Lifen Peng; Xinhua Xu; Yalei Zhao; Ruiren Tang


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
54 KB
Volume
29
Category
Article
ISSN
0256-7660

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ChemInform Abstract: Palladium-Catalyzed
✍ Xiaoyi Chen; Wei Kong; Haiting Cai; Lichun Kong; Gangguo Zhu πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 31 KB

## Abstract The palladium‐catalyzed haloallylation of alkynes (I) in dichloromethane leads stereoselectively to (E)‐dihalodienes (III), whereas (Z)‐isomers (IV) are readily obtained by the same reaction in acetic acid in the presence of lithium halides.