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Highly Stereoselective Ring Expansion of Enantiopure α-Hydroxyalkyl Azetidines.

✍ Scribed by Francois Couty; Francois Durrat; Damien Prim

Publisher
John Wiley and Sons
Year
2003
Weight
131 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

Ring Expansion of 2-(1-Hydroxyalkyl)azet
Ring Expansion of 2-(1-Hydroxyalkyl)azetidines to 4-(2-Chloroethyl)oxazolidinones
✍ François Couty; Bruno Drouillat; Frédéric Lemée 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 557 KB

## Abstract 2‐(1‐Hydroxyalkyl)azetidines react with bis(trichloromethyl) carbonate (BTC) after basic treatment to afford 4‐(2‐chloroethyl)oxazolidinones. The scope of this rearrangement was examined in detail and its efficiency was shown to depend on the class of the reacting alcohol and on the sub