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Highly stereoselective preparation of tri- and tetra-substituted olefins via β-tributylstannyl-α,β-unsaturated ketones

✍ Scribed by Takeshi Takeda; Yuki Kabasawa; Tooru Fujiwara


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
544 KB
Volume
51
Category
Article
ISSN
0040-4020

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## Reduction of a-methyl-B,y-unsaturated ketones with L-Selectride proceeded with high threo-selectivity to afford three-B-methyl homoallylic __-__alcohols of high enantio-and diastereomerica2 purities.