Enantio- and diastereomerically pure threo-homoallylic alcohols via highly stereoselective reduction of α-methyl-β,γ-unsaturated ketones

✍ Scribed by Keisuke Suzuki; Eiji Katayama; Gen-ichi Tsuchihashi

• Publisher: Elsevier Science
• Year: 1984
• Tongue: French
• Weight: 266 KB
• Volume: 25
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)81209-0

✦ Synopsis

Reduction of a-methyl-B,y-unsaturated ketones with L-Selectride proceeded with high threo-selectivity to afford three-B-methyl homoallylic __-__alcohols of high enantio-and diastereomerica2

purities.