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Highly stereoselective photodimerization of 1,3-dimethylthymine in liquid crystalline media

โœ Scribed by Takehisa Kunieda; Toshie Takahashi; Masaaki Hirobe

Book ID
104226271
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
152 KB
Volume
24
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Ordered media such as cholesteric and smectic solvents greatly enhance the stereoselectivity and the rate in photodimerization of 1,3_dimethylthymine, in contrast to the isotropic phase reactions leading to a poor product-selectivity.

There has been considerable current interest in the chemical effects produced by organized molecular assemblies such as miscelles, monolayers and liquid crystals.

1-3 This is primarily because of their analogies to some biological systems such as membranes and related structures.

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