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Highly efficient syntheses of 3-aryl-2-cycloalken-1-ones and an evaluation of their liquid crystalline properties

✍ Scribed by C.M Marson; L.D Farrand; R Brettle; D.A Dunmur

Book ID
104205320
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
153 KB
Volume
59
Category
Article
ISSN
0040-4020

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✦ Synopsis

Cycloalkenones are shown to be mesogens and can be synthesised in near quantitative yields by a convergent palladium(0)catalysed cross-coupling strategy; a 2-methyl group induces a change of phase from smectic to nematic.

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