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Highly Stereoselective Oxidative Esterification of Aldehydes with β-Dicarbonyl Compounds.

✍ Scribed by Woo-Jin Yoo; Chao-Jun Li


Book ID
101992281
Publisher
John Wiley and Sons
Year
2006
Weight
23 KB
Volume
37
Category
Article
ISSN
0931-7597

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Highly stereoselective reaction ofα-meth
✍ Masayuki Shimagaki; Hideki Takubo; Takeshi Oishi 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 217 KB

The reaction of a-methylthio aldehydes 4(R=1°, 2') with allyltriphenylstannane 5 in the presence of SnC14 gave anti-8-methylthio alcohols 6 in excellent selectivity. In connection with the recent findings that conversion of B-alkylthio alcohols 2 and 3 into olefins' or epoxides 2 proceeds with comp