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Competitive reactions of β-dicarbonyl and β-aminovinylcarbonyl compounds with aldehydes in the synthesis of hexahydroquinolines

✍ Scribed by A. Ya. Dreimane; É. É. Grinshtein; É. I. Stankevich

Book ID
112744193
Publisher
Springer US
Year
1980
Tongue
English
Weight
468 KB
Volume
16
Category
Article
ISSN
0009-3122

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The reaction of tetramethoxyethylene wit
The reaction of tetramethoxyethylene with β-dicarbonyl compounds
✍ P. Camps; J.M. Drudis 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 129 KB

Tetranethoxyethylene (TIIE) is a highly nucleophilic alkene that reacts with methanol, malononitrile or benmic acid to give the addition products, pentaoethoxyethane, 1,2,2~trimethoxyethyltdenemalononitrile and 1,1,2,2-tetramethoxyethyl benxoate respectively'. Roreover, the last product decomposes t