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Highly Stereoselective Intramolecular Addition of a Hydroxyl Group to Vinylsilanes via 1,2-Silyl Migration 1

โœ Scribed by Miura, Katsukiyo; Hondo, Takeshi; Saito, Hiroshi; Ito, Hajime; Hosomi, Akira


Book ID
127081503
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
123 KB
Volume
62
Category
Article
ISSN
0022-3263

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The 2-methylbut-2-enyl(diphenyl)silyl gr
โœ Ian Fleming; Stephen B.D. Winter ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 260 KB

The 2-mcthylbut-2-cnyl(diphcnyl)silyl group can be introduced into a variety of organic strucwrcs by way of the cuprate reagent 4. and h can then be converted into a hydroxyl group, even in Ihc prcscnce or a C=C double bond,