The 2-methylbut-2-enyl(diphenyl)silyl group: A silyl group easily converted to hydroxyl in the presence of a 1,2-disubstituted CC double bond

✍ Scribed by Ian Fleming; Stephen B.D. Winter

• Publisher: Elsevier Science
• Year: 1993
• Tongue: French
• Weight: 260 KB
• Volume: 34
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)79310-5

✦ Synopsis

The 2-mcthylbut-2-cnyl(diphcnyl)silyl group can be introduced into a variety of organic strucwrcs by way of the cuprate reagent 4. and h can then be converted into a hydroxyl group, even in Ihc prcscnce or a C=C double bond,