Optically active trans-4-(tert-butyldimethylsiloxymethyl)-5-(tert-butyldimethylsiloxy)-2-cyclohexenone (2) has been synthesized in 25% overall yield starting from easily available 1,4-bis(benzyloxy)-2,3-epoxy butane (3). The enone 2 reacts with excellent stereoselectivity with RCu(CN)Li thus working
β¦ LIBER β¦
Highly Stereoselective and Stereodivergent Synthesis of Four Types of THF Cores in Acetogenins Using a C 4 -Chiral Building Block
β Scribed by Maezaki, Naoyoshi; Kojima, Naoto; Asai, Mikito; Tominaga, Hiroaki; Tanaka, Tetsuaki
- Book ID
- 126831206
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 91 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1523-7060
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