ChemInform Abstract: Stereocontrolled To
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I. KADOTA; Y. YAMAMOTO
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Article
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2010
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John Wiley and Sons
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Stereocontrolled Total Synthesis of Hemibrevetoxin B. -A linear approach to the total synthesis of title compound (I) is accomplished with high stereoselectivity in 56 steps and 0.75% overall yield from D-mannose. Key step in this synthesis is the intramolecular reaction of ฮณ-alkoxyallylstannanes wi